Determination of the activation rate constants of alkyl halide initiators for atom transfer radical polymerization

1999 ◽  
Vol 20 (12) ◽  
pp. 633-636 ◽  
Author(s):  
Atsushi Goto ◽  
Takeshi Fukuda
Keyword(s):  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Rate Constants ◽  
Alkyl Halide ◽  
Atom Transfer ◽  
Activation Rate

scholarly journals Determination of Rate Constants for the Activation Step in Atom Transfer Radical Polymerization Using the Stopped-Flow Technique

2004 ◽  
Vol 37 (8) ◽  
pp. 2679-2682 ◽  
Author(s):  
Tomislav Pintauer ◽  
Wade Braunecker ◽  
Edmond Collange ◽  
Rinaldo Poli ◽  
Krzysztof Matyjaszewski
Keyword(s):  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Rate Constants ◽  
Stopped Flow ◽  
Atom Transfer

scholarly journals Electrochemical approaches to the determination of rate constants for the activation step in atom transfer radical polymerization

2016 ◽  
Vol 222 ◽  
pp. 393-401 ◽  
Author(s):  
Marco Fantin ◽  
Abdirisak A. Isse ◽  
Nicola Bortolamei ◽  
Krzysztof Matyjaszewski ◽  
Armando Gennaro
Keyword(s):  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Rate Constants ◽  
Atom Transfer

Well-defined polymers containing a single mid-chain viologen group: synthesis, environment-sensitive fluorescence, and redox activity

2016 ◽  
Vol 7 (26) ◽  
pp. 4402-4410 ◽  
Author(s):  
Zhaoxu Wang ◽  
Nicolay V. Tsarevsky
Keyword(s):  
Methyl Methacrylate ◽  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Alkyl Halide ◽  
Redox Activity ◽  
Atom Transfer ◽  
Redox Catalysts

A difunctional viologen-based alkyl halide initiator was employed in the atom transfer radical polymerization of methyl methacrylate, which afforded well-defined polymers with a single mid-chain viologen functionality. The materials were fluorescent and also served as redox catalysts.

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